The Thermal Decomposition of Ethyl Mercaptan and Ethyl Sulphide. A Reply
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چکیده
منابع مشابه
Kinetic Study of Ethyl Mercaptan Oxidation in Presence of Merox Catalyst
Mercaptans are commonly present in petroleum products. Their foul odor and highly corrosive nature make them the most undesirable sulfur compounds so they should be removed because of environmental issues. Merox process is used for oxidation of mercaptans to disulfide using air in the presence of alkaline solution and Merox catalyst. In this paper, due to lack of information about the kinet...
متن کاملTheoretical spectroscopic characterization at low temperatures of detectable sulfur-organic compounds: ethyl mercaptan and dimethyl sulfide.
Highly correlated ab initio methods are used for the spectroscopic characterization of ethyl mercaptan (CH3CH2 (32)SH, ETSH) and dimethyl sulfide (CH3 (32)SCH3, DMS), considering them on the vibrational ground and excited torsional states. Since both molecules show non-rigid properties, torsional energy barriers and splittings are provided. Equilibrium geometries and the corresponding rotationa...
متن کاملKinetic Study of Ethyl Mercaptan Oxidation in Presence of Merox Catalyst
Mercaptans are commonly present in petroleum products. Their foul odor and highly corrosive nature make them the most undesirable sulfur compounds so they should be removed because of environmental issues. Merox process is used for oxidation of mercaptans to disulfide using air in the presence of alkaline solution and Merox catalyst. In this paper, due to lack of information about the kinetic o...
متن کاملthe investigation of the relationship between type a and type b personalities and quality of translation
چکیده ندارد.
On the cause of low thermal stability of ethyl halodiazoacetates
Rates for the thermal decomposition of ethyl halodiazoacetates (halo = Cl, Br, I) have been obtained, and reported herein are their half-lives. The experimental results are supported by DFT calculations, and we provide a possible explanation for the reduced thermal stability of ethyl halodiazoacetates compared to ethyl diazoacetate and for the relative decomposition rates between the chloro, br...
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ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 1933
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.1749286